Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. The purpose of this App Note is to present the precision achievable with an HMJ Y501 Dual Capillary Relative Viscometer (DSV) system. The analysis conditions are listed below.
Solvent |
60/40, Phenol/Tetrachloroethane |
Sample Concentration |
1 g/dL |
Prep Temperature |
25C |
Dissolution Time |
60 Minutes |
Analysis Temperature |
19C |
The data summary clearly shows the superior precision of the instrument. RSD of DSV data is typically less than 1% and the following data supports that claim.
Samples |
IV |
Sample |
IV |
Sample |
IV |
1A-1 |
0.4553 |
2A-1 |
0.4847 |
3A-1 |
0.3943 |
1A-2 |
0.4608 |
2A-1 |
0.4819 |
3A-2 |
0.3944 |
1B-1 |
0.4524 |
2B-1 |
0.4877 |
3B-1 |
0.3952 |
1B-2 |
0.4604 |
2B-2 |
0.4803 |
3B-2 |
0.3959 |
Average |
0.4572 |
Average |
0.4837 |
Average |
0.3950 |
SD |
0.0041 |
SD |
0.0033 |
SD |
0.0008 |
RSD |
0.89% |
RSD |
0.67% |
RSD |
0.19% |
In addition to the precision of the data demonstrated above, the relative viscometer presents an easy opportunity to automate a particularly laborious task. Automation can range from a simple autosampler system to fully automated Vortex operation.