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          • Dilute Solution Viscosity Measurement of Gelatins
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          • Dilute Solution Viscosity Measurement of Polylactide
          • Dilute Solution Viscosity Measurement of Poly(Methyl Methacrylate)
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          • Dilute Solution Viscosity Measurement of Polyvinylpyrrolidone
          • Dilute Solution Viscosity Measurement of HMW Rubber
          • High Temperature Dilute Solution Viscosity Measurement of Gilsonite®
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          • Dilute Solution Viscosity Measurement of Gelatins
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          • Dilute Solution Viscosity Measurement of Polyethylene Terephthalate
          • Dilute Solution Viscosity Measurement of Polylactide
          • Dilute Solution Viscosity Measurement of Poly(Methyl Methacrylate)
          • Dilute Solution Viscosity Measurement of Polyacrylonitrile
          • Dilute Solution Viscosity Measurement of Polycarbonate
          • Dilute Solution Viscosity Measurement of Polyolefins
          • Dilute Solution Viscosity Measurement of Polystyrene
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          • Dilute Solution Viscosity Measurement of Polyvinylpyrrolidone
          • Dilute Solution Viscosity Measurement of HMW Rubber
          • High Temperature Dilute Solution Viscosity Measurement of Gilsonite®
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          • Dilute Solution Viscosity Measurement of HMW Polyethylene
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Dilute Solution Viscosity Measurement of Polyethylene Terephthalate

Polyethylene terephthalate (PET) is the most common thermoplastic polymer resin of the polyester family and is used in fibers for clothing, containers for liquids and foods, thermoforming for manufacturing, and in combination with glass fibers for engineering resins. The majority of the world's PET production is for synthetic fibers (in excess of 60%), with bottle production accounting for about 30% of global demand. PET consists of polymerized units of the monomer ethylene terephthalate, with repeating (C10H8O4) units. PET is also commonly recycled. Depending on its processing and thermal history, polyethylene terephthalate may exist both as an amorphous or a semi-crystalline polymer. The semi-crystalline material may require more vigorous conditions for dissolution. The purpose of the analysis is to determine the repeatability of this PET DSV method. The samples were analyzed using an HMJ Y501 Dual Capillary Relative Viscometer (DSV) system. The analysis conditions are listed below.
Solvent
60/40, Phenol/Tetrachloroethane
Sample Concentration
0.5 g/dL
Prep Temperature
110C
Dissolution Time
60 Minutes
Analysis Temperature
30C
RSD of DSV data is typically less than 1% and the following data supports that claim.
Samples
IV (dL/g)
 
Samples
IV (dL/g)
 
 
 
 
 
PET-1A
0.6255
 
PET-3A
0.6273
PET-1B
0.6261
 
PET-3B
0.6316
PET-2A
0.6266
 
PET-4A
0.6330
PET-2B
0.6292
 
PET-4B
0.6256
​In addition to the precision of the data demonstrated above, the relative viscometer presents an easy opportunity to automate a particularly laborious task. Automation can range from a simple autosampler system to fully automated Vortex operation.

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    • Linkoptik Learning >
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      • DSV Learning >
        • Principles of Dilute Solution Viscosity
        • DSV Application Notes >
          • Dilute Solution Viscosity Measurement of Gelatins
          • Dilute Solution Viscosity Measurement of Polylamide
          • Dilute Solution Viscosity Measurement of Polyethylene Terephthalate
          • Dilute Solution Viscosity Measurement of Polylactide
          • Dilute Solution Viscosity Measurement of Poly(Methyl Methacrylate)
          • Dilute Solution Viscosity Measurement of Polyacrylonitrile
          • Dilute Solution Viscosity Measurement of Polycarbonate
          • Dilute Solution Viscosity Measurement of Polyolefins
          • Dilute Solution Viscosity Measurement of Polystyrene
          • Dilute Solution Viscosity Measurement of Polyvinyl Chloride
          • Dilute Solution Viscosity Measurement of Polyvinylpyrrolidone
          • Dilute Solution Viscosity Measurement of HMW Rubber
          • High Temperature Dilute Solution Viscosity Measurement of Gilsonite®
          • Dilute Solution Viscosity Measurement of Polyolefins
          • Dilute Solution Viscosity Measurement of HMW Polyethylene
          • Dilute Solution Viscosity Measurement of HMW Polyethylene
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