Polylamide is one of the most widely used thermoplastic in the world. It can be processed into films, fibers or shapes. Nylon 6 and Nylon 6-6 are the two most common grades within the Polyamide family. They are similar in structure and properties. Nylon 6 is formed by ring-opening polymerization of Caprolactam. Nylon 6-6 is the product of a condensation reaction between Hexamethylenediamine and Adipic Acid. Applications of these materials include Carpets, Apparels, Airbags, Tires, Zip Ties, Ropes, Conveyor Belts and Hoses etc. The purpose of this App Note is to present the precision achievable with an HMJ Y501 Dual Capillary Relative Viscometer (DSV) system. The analysis conditions are listed below.
Solvent |
88% Formic Acid |
Sample Concentration |
1 g/dL |
Prep Temperature |
25C |
Dissolution Time |
60 Minutes |
Analysis Temeprature |
30C |
The data summary clearly shows the superior precision of the instrument. RSD of DSV data is typically less than 1% and the following data supports that claim.
Samples |
IV (dL/g) |
Samples |
IV (dL/g) |
Samples |
IV (dL/g) |
||
DK1A1 |
1.0869 |
DK2A1 |
1.0707 |
DK3A1 |
1.0438 |
||
DK1A2 |
1.0881 |
DK2A2 |
1.0655 |
DK3A2 |
1.0314 |
||
DK1B1 |
1.0939 |
DK2B1 |
1.0693 |
DK3B1 |
1.0376 |
||
DK1B2 |
1.0945 |
DK2B2 |
1.0716 |
DK3B2 |
1.0368 |
||
Average |
1.0909 |
Average |
1.0693 |
Average |
1.0374 |
||
SD |
0.0039 |
SD |
0.0027 |
SD |
0.0051 |
||
RSD |
0.36% |
RSD |
0.25% |
RSD |
0.49% |
In addition to the precision of the data demonstrated above, the relative viscometer presents an easy opportunity to automate a particularly laborious task. Automation can range from a simple autosampler system to fully automated Vortex operation.