Poly(Methyl Methacrylate) (PMMA) is a synthetic organic polymer made from the polymerization of Methyl Methacrylate monomers. PMMA is commonly known as Acrylic or Plexiglas. Through a simple polymerization process, it can be formed into sheets, blocks or pellets. PMMA is a relatively inexpensive material. It is also clear, light and tough which make it an ideal substitute for certain glass applications. Typically, PMMA is found in bank teller partitions, windows, ice hockey rinks and aquariums. Solution Viscosity is a key property control in the manufacturing process. The purpose of this App Note is to demonstrate the repeatability of the HMJ DSV technique. The samples were analyzed using an HMJ Y501 Dual Capillary Relative Viscometer system. The analysis conditions are listed below.
Solvent |
THF |
Sample Concentration |
0.5 g/dL |
Prep Temperature |
25C |
Dissolution Time |
60 Minutes |
Analysis Temperature |
30C |
RSD of DSV data is typically less than 1% and the following data supports that claim.
Samples |
IV (dL/g) |
Sample |
IV (dL/g) |
|
Virgin 1A |
4.0641 |
Processed 1A |
3.4034 |
|
Virgin 1B |
4.0540 |
Processed 1B |
3.4062 |
|
Virgin 2A |
4.0155 |
Processed 2A |
3.4099 |
|
Virgin 2B |
4.0062 |
Processed 2B |
3.4066 |
|
Average |
4.0350 |
Average |
3.4065 |
|
SD |
0.0284 |
SD |
0.0027 |
Average = 0.3458 SD = 0.0018 RSD = 0.52% |
In addition to the precision of the data demonstrated above, the relative viscometer presents an easy opportunity to automate a particularly laborious task. Automation can range from a simple autosampler system to fully automated Vortex operation.